What Is Conductometric Titration?

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Written By Charlotte Miller

Are you curious to know what is conductometric titration? You have come to the right place as I am going to tell you everything about conductometric titration in a very simple explanation. Without further discussion let’s begin to know what is conductometric titration?

In the realm of analytical chemistry, conductometric titration stands as a valuable technique used to determine the concentration of a chemical species in a solution. This method relies on the measurement of electrical conductivity changes during a titration process. In this blog post, we will explore what conductometric titration is, its principles, applications, and its significance in quantitative analysis.

What Is Conductometric Titration?

Conductometric titration involves the gradual addition of a titrant solution of known concentration to an analyte solution of unknown concentration. Throughout the titration, electrical conductivity measurements are recorded, reflecting changes in ion concentration and the conductive properties of the solution. The titration endpoint is reached when a significant change in conductivity occurs, indicating that the reaction between the analyte and titrant is complete.

The conductivity of a solution is directly proportional to the concentration of ions present. During a titration, the addition of the titrant alters the concentration of ions in the solution, leading to changes in conductivity. The graph of conductivity versus volume of titrant added typically exhibits distinct regions, including a sharp change at the equivalence point, which corresponds to the stoichiometric completion of the reaction.

Applications Of Conductometric Titration

  1. Acid-Base Titration: Conductometric titration is commonly employed in the determination of acid and base concentrations. By using a suitable indicator or pH electrode, the conductivity changes throughout the titration process can be accurately measured, providing valuable information for acid-base equilibrium calculations.
  2. Redox Titration: Conductometric titration is also utilized in redox reactions, where the transfer of electrons occurs. The changes in conductivity during the titration reflect the variation in the concentration of ions involved in the redox reaction, aiding in the determination of the analyte’s concentration.
  3. Precipitation Titration: In precipitation titrations, conductometric measurements can assist in determining the endpoint where the formation of a precipitate occurs. The conductivity changes as the precipitate forms, enabling precise determination of the analyte concentration.
  4. Complexometric Titration: Conductometric titration plays a significant role in complexometric titrations, where metal ions form complexes with specific ligands. The formation and subsequent complexation of ions during the titration can be monitored through conductivity measurements, leading to the determination of metal ion concentrations.

Significance Of Conductometric Titration In Quantitative Analysis

  1. High Sensitivity: Conductometric titration is a highly sensitive technique that can detect small changes in conductivity. This sensitivity allows for precise determination of the endpoint, enhancing the accuracy of quantitative analysis.
  2. Versatility: Conductometric titration is applicable to a wide range of chemical reactions and analytes, making it a versatile analytical technique. It can be employed in various industries, including pharmaceuticals, environmental analysis, and food science.
  3. Real-Time Monitoring: Conductometric titration provides real-time monitoring of the titration process, allowing for prompt identification of the endpoint. This feature enables researchers and analysts to optimize experimental conditions and obtain accurate results efficiently.
  4. Cost-Effective: Conductometric titration is a cost-effective analytical method compared to other techniques. The required equipment, such as conductivity meters and electrodes, is relatively affordable and readily available in most laboratories.


Conductometric titration is a powerful analytical technique used to determine the concentration of chemical species in a solution. By measuring changes in electrical conductivity during the titration process, conductometric titration enables accurate and precise quantitative analysis. Its versatility, sensitivity, and real-time monitoring capabilities make it a valuable tool in various fields of chemistry and industry. As technology continues to advance, conductometric titration will likely continue to evolve, further enhancing its applications and contributing to the advancement of analytical chemistry.


What Do You Mean By Conductometric Titration?

The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point is reached. The titration is monitored by measuring the conductance of the solution.

What Are The Types Of Conductometric Titration?

Types of conductometric titrations:

  • Acid-base titration.
  • Precipitation titration.
  • Replacement titration.
  • Redox (oxidation-reduction) titration.
  • Complexometric titration.

What Is The Difference Between Conductometric Titration And Normal Titration?

What is the Difference Between Potentiometric and Conductometric Titrations? The key difference between potentiometric and conductometric titrations is that potentiometric titrations measure the potential across the analyte, whereas conductometric titrations measure the electrolytic conductivity of the analyte.

What Is The Unit Of Conductometry?

Conductometry is the measurement of the electrical conductivity of a solution. The conductance is defined as the current flow through the conductor. In other words, it is defined as the reciprocal of the resistance. The unit for the conductance is Seimens (S) which is the reciprocal of Ohm’s (Ω −1).

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